I take it this is a new installation. First, check things with a timing light and make sure your spark is happening when MegaTune says it is. If it isn't, adjust the trigger angle setting and get that fixed. After that, you'll need to adjust the cranking pulse widths to get the engine to catch - even if it dies in a few seconds. Once it's at that point, put in some temporary settings for afterstart enrichment, nurse it along till you can get the engine to warm up, and dial in the VE table at idle with the engine hot. You'll fill in permanent values for the ASE and warm up enrichment settings on later cold starts.